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双(三苯基膦)醋酸钯 |
| CAS No.: |
14588-08-0 |
| 分子式： |
C40H36O4P2Pd |
| 分子量： |
749.09 |
| 备注： |
中文名称双(三苯膦基)醋酸钯(II)中文同义词二(三笨基膦)二(乙酸)钯(LL);三苯基膦醋酸钯;二(乙酰丙酮)三苯基膦钯;二(三苯基膦)二(乙酸)钯(II);二(三苯基膦)二乙酸钯(II)PD>14.3;二(三苯基膦)二乙酸钯(II)1G;三苯基膦醋酸钯PD(OAC)2(PPH3)2;二乙酰基双(三氟苯基磷)钯(II),PD14.2%英文名称Bis(triphenylphosphinepalladium)acetate英文同义词Diacetatobis(triphenylphosphine)palladium(II)Storerefrigerated;Bis(acetato)bis(triphenylphosphine)palladium(II),Palladium(II)bis(triphenylphosphine)diacetate;Palladium,bis(acetato-O)bis(triphenylphosphine)-;Diacetatobis(triphenylphosphine)palladium(II),Pd14.2%;Diacetatobis(Triphenylphosphosphate)PalladiuM;Bis(triphenylphosphine)palladium(II)acetate,99%;Diacetatobis(triphenylphosphine)palladiuM(II),98%(PPh3)2Pd(OAc)2;Bis(triphenylphosphinepalladiuCAS号14588-08-0分子式C40H36O4P2Pd分子量749.08EINECS号238-628-4相关类别金属催化剂;贵金属;钯;医药中间体;金属化合物;催化和无机化学;有机贵金属;有机贵重金属;膦配体;通用试剂;贵金属催化剂;含钯催化剂;化工中间体;MetalCompounds;CatalystsforOrganicSynthesis;ClassesofMetalCompounds;HomogeneousCatalysts;MetalComplexes;PdChemicalbook(Palladium)Compounds;SyntheticOrganicChemistry;TransitionMetalCompounds;metal-phosphinecomplexes;chemicalreaction,pharm,electronic,materials;HalogenatedHeterocycles,Pyrimidines;Pd;中间体-有机中间体Mol文件14588-08-0.mol结构式双(三苯膦基)醋酸钯(II)性质熔点136°C(dec.)(lit.)储存条件Inertatmosphere,Storeinfreezer,under-20°C形态粉末颜色粘黄色稳定性冷藏InChIInChI=1S/2C18H15P.2C2H4O2.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2(3)4;/h2*1-15H;2*1H3,(H,3,4);/q;;;;+2/p-2InChIKeyOZELLBKLLRMCRL-UHFFFAOYSA-MSMILESP(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1C=CC=CC=1)(C1=CC=CC=C1)C1=CC=CC=C1.O(C(=O)C)[Pd]OC(=O)C双(三苯膦基)醋酸钯(II)用途与合成方法概述双(三苯膦基)醋酸钯(II)在交叉偶合反应、铃木偶联反应中催化性能优异，在医药工业和有机工业中有着广泛的应用。制备将0.2gPd(AC)2溶解于10mL冰醋酸(也可采用甲苯、二氯甲烷、二甲基亚砜或N-N-二甲基甲酰胺)中得醋酸钯溶液，将0.5gPPh3溶解于30mL无水乙醇(也可采用二氯甲烷、甲苯、二甲基亚砜或N-N-二甲基甲酰胺)中得三苯基膦溶液，将醋酸钯溶液加入三苯基膦溶液中，超声60℃反应5h后冷却，过滤，得到黄色结晶钯配合物，收率为98.5％，产物质量纯度为99.5％。用途有机试剂，医药中间体。Bis(triphenylphosphine)palladium(II)diacetate |
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