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二聚醋酸铑 |
CAS No.: |
15956-28-2 |
分子式: |
C8H12O8Rh2 |
分子量: |
441.99 |
备注: |
中文名称二聚醋酸铑中文同义词醋酸铑二聚体1G;乙酸铑(II)二聚物二水合物;二水醋酸铑(II)二聚体;乙酸铑(II)二聚体,无水;乙酸铑(Ⅱ)二聚体,42%铑,UMICORE制造;醋酸铑(II)二聚体;二聚醋酸铑;二聚醋酸铑[RH(CH3CO2)]2·2H2O46.5%英文名称Rhodium(II)acetatedimer英文同义词tetrakis-(mu-acetato)dirhodium;Rhodium(Ⅱ)acetatedimer,99%[anhydrous,46%Rh];Rhodium(II)acetatedimerdihydrate,Dirhodiumtetraacetate,Tetrakis(acetato)dirhodium(II);Rhodium(II)acetatedimer,Dirhodiumtetraacetate,Tetrakis(acetato)dirhodium(II);tetrakis[mu-(acetato-O:O’)]dirhodium;RHODIUM(II)ACETATEDIMER,POWDER;RHODIUM(II)ACETATEDIMER,99.99+%METALSBASIS;RhodiuM(II)acetatediMer,anhydrous,ca46%Rh1GRCAS号15956-28-2分子式C8H12O8Rh2分子量441.99EINECS号240-084-8相关类别含铑催化剂;催化和无机化学;贵金属催化剂;金属有机物;合成材料中间体;贵金属;通用试剂;铑;铑催化Chemicalbook剂;金属催化剂;贵金属化合物;吡啶-1;CatalystsforOrganicSynthesis;ClassesofMetalCompounds;HomogeneousCatalysts;MetalComplexes;Rh(Rhodium)Compounds;SyntheticOrganicChemistry;TransitionMetalCompounds;metalacetatesalt;chemicalreaction,pharm,electronic,materials;Rh;化工原料;化工中间体Mol文件15956-28-2.mol结构式二聚醋酸铑性质熔点205°C储存条件Inertatmosphere,RoomTemperature溶解度可溶于甲醇+水(微溶)形态粉末颜色绿色至深绿色水溶解性Solubleinaqueoussolutionlikewater.Slightlysolubleinethanol水解敏感性0:formsstableaqueoussolutions暴露限值ACGIH:TWA0.01mg/m3NIOSH:IDLH2mg/m3;TWA0.001mg/m3稳定性吸湿性InChIKeyANSVJOOIUURYRN-UHFFFAOYSA-N二聚醋酸铑用途与合成方法化学性质二聚醋酸铑呈绿色结晶粉末状,溶于甲醇。它在水中可溶,而乙酸铜在水中相对溶解度小。用途烯烃的环丙烷化,同源催化剂,高效催化剂,用于ylideformation。用途烯烃的环丙烷化,同源催化剂,高效催化剂,用于形成叶立德。 |
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